Frank Derbyshire, Alan Davis, Mike Epstein and Peter Stansberry
Fuel Science Program, Coal Research Section, College of Earth and Mineral Sciences, The Pennsylvania State University, University Park, PA 16802, USA
Abstract
An investigation has been made of the liquefaction of a bituminous and a subbituminous coal under conditions where reaction is conducted in successive stages of increasing temperature and in the presence of a dispersed sulphided Mo catalyst. This sequence has been found to lead not only to high coal conversion but to greatly increase the selectivity of the liquefied products to oils at the expense of asphaltenes. These gains are made with marginal increases in the production of light hydrocarbon gases. Although no systematic attempt has yet been made to determine the specific influence of reaction parameters upon liquefaction behaviour, preliminary results show that there is substantial potential for further improvement through the suitable choice of solvent and reaction conditions in the two stages. The reasons for the effectiveness of temperature staged liquefaction are discussed in terms of the balance between hydrogenation and condensation reactions. Examination of the liquefaction residues by optical microscopy has provided strong supporting evidence to show that the staged reaction sequence favours hydrogenative processes. Moreover, the microscopic examination has proved to be a powerful diagnostic technique, showing, for example, that the first stage temperature should be lower for the subbituminous than the bituminous coal, and providing insight into the processes of catalysed liquefaction.