"Low energy packed tower and caustic recovery for direct capture of CO2 from air
M. Mahmoudkhan, K.R. Heide, J.C. Ferreira, D.W. Keith and R.S. Cherry
References
[1]J.G. Canadell, et al. Contributions to accelerating atmospheric CO2 growth from economic activity, carbon intensity and efficiency of natural sinks, in: Proceedings of the National Academy of Sciences, 104 (47), 2007, pp. 18866–18870.
[2]N.A. Spector and B.F. Dodge, Removal of carbon dioxide from atmospheric air, Trans. Am. Inst. Chem. Eng. 42 (1946), pp. 827–848.
[3]J.B. Tepe and B.F. Dodge, Absorption of carbon dioxide by sodium hydroxide solutions in a packed column, Trans. Am. Inst. Chem. Eng. 39 (1943), pp. 255–276.
[4]K.S. Lackner, P. Grimes, H.J. Ziock, Capturing carbon dioxide from air, in: 24th Annual Technical Conference on Coal Utilization: Clearwater, FL, 1999.
[5]R Baciocchi, G Storti and M. Mazzotti, Process design and energy requirement for the capture of carbon dioxide from air, Chemical Engineering and Processing 45 (2006), pp. 1047–1058.
[6]F. Zeman, Energy and material balance of CO2 capture from ambient air, Environmental Science & Technology 41 (2007), pp. 7558–7563.
[7]J.K. Storaloff, D.W. Keith and G.V. Lowry, Carbon dioxide capture from atmospheric air using sodium hydroxide spray, Environmental Science & Technology 42 (2008), pp. 2728–2735.
[8]F. Zeman and K. Lackner, Capturing carbon dioxide directly from the atmosphere, World Resource Review (2) (2004), pp. 157–172.
[9]X. Chen and A.R.P. van Heiningen, Kinetics of the direct causticizing reaction between sodium carbonate and titanium dioxide or sodium tri-titanate, Journal of Pulp and Paper Science 32 (4) (2006), pp. 245–251.
[10]E. Kiiskilä, Recovery of sodium hydroxide from alkaline pulping liquors by smelt causticizing, Part II. Recations between sodium carbonate and titanium dioxide, Paperi ja Puu, Papper och Trä 5 (1979), pp. 394–401.
[11]E. Kiiskilä, Recovery of sodium hydroxide from alkaline pulping liquors by smelt causticizing, Part III. Alkali distribution in titanium dioxide causticizing, Paperi ja Puu, Papper och Trä 6 (1979), pp. 453–464.
[12]I. Nohlgren, Recovery of kraft black liquor with direct causticization using titanates. Ph.D. Thesis, Lulea University of Technology, Lulea, Sweden, 2002.
[13]M. Palm and H. Theliander, Kinetic study of the direct causticization reaction involving titanates and titanium dioxide, Chemical Engineering Journal 68 (1997), pp. 87–94.
[14]L. Zeng and A.R.P. van Heiningen, Pilot fluidized-bed testing of kraft black liquor gasification and its direct causticization with TiO2, Journal of Pulp and Paper Science 23 (11) (1997), pp. J511–J516.
[15]X. Zou, Recovery of kraft black liquor including direct causticization, Ph.D. Thesis, McGill University, Montreal, Quebec, 1991.
[16]M. Mahmoudkhani, D.W. Keith, Low-energy sodium hydroxide recovery for CO2 capture from air, International Journal of Greenhouse Gas Control Technologies, In review, 2008."
Without citation, we remind you of earlier research we've reported wherein wastes from wood and paper processing, i.e., "black liquor", as named in the references above, have demonstrated potential for being co-processed with coal and coal by-products in the synthesis of useful organic chemicals. Such co-processing with a botanical product from wood pulping mills, etc., would represent a further recycling, or use, of carbon extracted, in such cases via photosynthesis, from the atmosphere.
Also, if you recall, we recently reported on other work by Canada's David Keith, and collaborators, in the technology for CO2 recycling, as in: "CARBON NEUTRAL HYDROCARBONS", by Frank Zeman and David W. Keith.