www.topsoe.com/sites/default/files/topsoe_jaramillo_semiconductors_catalysts.pdf
In our prior report of:
Stanford Converts CO2 to Methane | Research & Development | News; concerning the technical paper:
"Electrocatalytic conversion of carbon dioxide to methane and oxygen with an oxygen ion-conducting electrolyte; Authors: Gurt, T.M.; Wise, H.; Huggins, R.A.; Affiliation: Stanford University; Dept. of Materials Science Engineering; Stanford, CA; Publication: Journal of Catalysis, 1991, vol. 129, pp. 216-224; Abstract: The performance characteristics of a solid-state electrochemical cell have been examined for the catalytic conversion of carbon dioxide and hydrogen to methane and oxygen. The electrolyte, made up of yttria-stabilized zirconia (YSZ), served the dual function of (a) a support material for the platinum catalyst, and (b) an oxygen ion-conducting membrane for the removal of surface oxygen formed during the reaction. The results indicate a linear increase in reaction rate with DC bias applied across the solid electrolyte. The reaction proceeds by way of a stepwise abstraction of oxygen atoms from carbon dioxide and hydrogenation of surface carbon to methane";