WV Coal Member Meeting 2024 1240x200 1 1

Coal to Give Gasoline, Benefit Mankind - in 1962


 
In 1926, in the same era as Bergius won the Nobel Prize for converting coal into liquid fuel and Sabatier won the Nobel Prize for recycling Carbon Dioxide into even more fuel, the New York Times recognized the importance of converting our vast reserves of domestic coal into the liquid fuels people of genuine vision recognized, even then, that we would need to have, and have from our own, secure United States reserves.
 
An excerpt follows, but we'll close here with a question that must be asked: Why is it that journalists in New York City recognized, eight decades, almost a century, ago, that our US coal represents a vault of treasure locked away, literally, in our basement, but Coal State journalists, now, don't even seem to be looking for the key?
 
Just wondering.
 
Joe the Miner 
 
A brief excerpt:

COAL IS TO GIVE US GASOLINE AND A NEW FUEL; Chemists Promise a Rich Source of Future Energy to be Produced in Factories -- How Bituminous Mines are to be Utilized for the Benefit of Mankind

By VALENTINE KARLYN

November 28, 1926, Sunday

Section: SPECIAL FEATURES AUTOMOBILES SPECIAL FEATURES RADIO, Page XX3, 3273 words

A THOUSAND chemists and fuel engineers saw the future of coal unfolded during the international conference on bituminous coal held in Pittsburgh a few days ago. Scientists from England, Germany and France vied with American technologists in foreshadowing a day when the burning of raw coal in the factory or the home will be regarded as a highly extravagant practice.

WVU Patents CTL

 
It is, unfortunately, not Coal-to-Liquid technology that WVU has patented. China, as we some time ago reported to you, has Shanghaied WVU's "West Virginia Process" for direct coal liquefaction, and applied for their own US and/or International Patent(s) on the technology; again, as we much earlier documented.
 
That info is in the WV Coal Association R&D Blog archives.
 
However, as a sort of consolation prize, WVU has, apparently, been awarded a US patent for converting Corpses and Cow pies To Liquid fuel.
 
An excerpt from the link, edited somewhat for concision:
 
"Title: Method of converting animal waste into a multi-phase fuel
 
Patent Number: US2008271363 - November 06, 2008
 
Inventors: Stiller;  Alfred Herman and Eddy;  Laura Shannon
 
Assignee: West Virginia University
 
Abstract and Claims:

A method of creating a multi-phase fuel wherein said fuel comprises a gas, a solid, a liquid solvent phase and an aqueous phase from animal waste comprising the combination of the animal waste, a solvent, and a water/alcohol solution into a fluid mixture, placing the mixture into a closed reactor, heating said reactor between about 245.degree. C. and 385.degree. C. for between about 5 and 70 minutes and cooling said resulting multi-phase fuel. The animal waste may be manure, mortalities, municipal waste, or chicken litter. The preferred solvent is petroleum with the preferred petroleum being diesel fuel. The final multi-phase fuel can be separated into four separate fuels: a solid fuel, an emulsified solid in the liquid solvent phase by blending the solid, the solvent and a surfactant, an aqueous phase, and the recovered liquid solvent phase. Petroleum is the preferred solvent and the separation may be any conventional means. The mixture preferably consists of 1 part by weight animal waste, about 1.5 parts by weight diesel and between about 0.11 to about 1.86 parts by weight a water/alcohol solution. The water/alcohol solution is between about 5% to about 85% alcohol before heating. Additionally, an alkali base may be added to increase waste solubility.

1. A fuel reactant mixture comprising about 1 part by weight animal waste, about 1.5 parts by weight petroleum based solvent and between about 0.11 to about 1.86 parts by weight a water/alcohol solution, wherein said water/alcohol solution is between about 5% to about 85% alcohol. 3. The fuel reactant mixture of claim 1 wherein said animal waste is selected from one or more of the group consisting of manure, mortalities, municipal waste, and chicken litter. 4. The fuel reactant mixture of claim 1 wherein said petroleum based solvent is diesel. 5. The fuel reactant mixture of claim 1 further comprising adding an alkali base to said mixture. 6. The fuel reactant mixture of claim 5 wherein said alkali base is sodium hydroxide. 7. The fuel reactant mixture of claim 1 wherein said alcohol is normal propyl alcohol. 8. The fuel reactant mixture of claim 1 wherein said water/alcohol solution is about 25% alcohol. 9. The fuel reactant mixture of claim 1 wherein said water/alcohol solution is about 1 part per weight. 10. The fuel reactant mixture of claim 1 further comprising mixing said animal waste, said petroleum based solving, and said water/alcohol solution into a fluid solution. 11. The fuel reactant mixture of claim 10 further comprising heating said mixture for an effective time and effective heat to produce a multi-phase fuel. 12. The fuel reactant mixture of claim 11 wherein said multi-phase fuel is further comprised of an aqueous phase fuel, a liquid solvent phase fuel, a solid fuel, and a gas."

We congratulate, of course, WVU on this achievement. The conversion of any bio-based resource into liquid fuel represents a step forward in both domestic liquid fuel self-sufficiency and carbon recycling.

But: We are allowing China to patent the West Virginia Process for direct coal liquefaction, and we have herein only a consolation prize. We Mountaineers, while paying royalties to China, when we eventually get around to converting our vast reserves of coal into the liquid fuels we need, will be able to liquefy, free of foreign charges, all the animal corpses and manure we can scrape together. Does that mean we'll be converting ourselves into liquid fuel? One might think so, since, if we do allow the game play out the way it appears, then we are, and will remain, really, nothing more than horses' patoots, full of BS.

Nation Must Use Unconventional Oil

 

We've never heard of C. John Mann, and doubt many in our local corner of Coal Country have either.
 
But, we should all be talking, and writing, like him.
 
There's not much new in here, except that Mann is neither a politician nor a journalist. He is, though, as some research reveals, an accomplished scientist; a Mann of learning, so to speak. He knows what he's talking about, and we all should be listening.
 
And, again, writing.
 
The excerpt:
 
C. John Mann: Nation must use oil from unconventional sources

 
THE STATE JOURNAL-REGISTER
Posted Oct 27, 2009 @ 01:02 AM

All but ardent environmentalists who have a perverse antipathy toward science seem to recognize that continued use of fossil fuels is inevitable. What is not inevitable is a costly energy crisis that results from an over-emphasis on unreliable energy sources and neglect of oil, natural gas and coal.

Though they’re helpful in meeting energy demand in some parts of the country, solar and wind energy are too undependable to run factories and keep the lights on in cities. Solar and wind can’t move the nation’s transportation system. Nor can biofuels. For America’s motor vehicles, we’re still going to rely on gasoline and diesel. But our foreign-oil dependence is about to get much worse unless something is done about it.

If the Obama administration is really interested in reducing U.S. reliance on foreign energy supplies, then it should recognize the value and validity of unconventional oil made from liquefied coal, Canadian oil sands and Western oil shale.

Using these vast resources to meet America’s energy needs would be a boon for U.S. consumers and this country’s energy security. And everyone would benefit from well-paying jobs and revenue that come from producing, processing and refining liquefied coal and oil sands.

A recent decision by the U.S. State Department to support oil-sands production offers at least a glimmer of foresight and flexibility.

Canada’s oil sands formations hold an estimated 173 billion barrels of recoverable oil, making Canada second only to Saudi Arabia in the size of its reserves. The International Energy Agency has said that with future advances in technology as much as 1.7 trillion barrels of Canadian oil sands could be extracted.

Despite protests from environmental groups, the State Department approved a permit for a 1,000-mile-long pipeline that would carry oil from Canada’s oil sands formations in northern Alberta to refineries on Lake Superior in Wisconsin. The Alberta Clipper pipeline will be capable of carrying 800,000 barrels per day of crude oil, shoring up Canada’s position as America’s No. 1 source of foreign oil.

Environmentalists, however, are waging an all-out battle against the use of oil sands, largely on grounds that it is more carbon-intensive than conventional crude oil, as if the crucial role of unconventional oil in meeting America’s energy needs doesn’t matter.

Environmental groups have filed lawsuits to block expansion of the vast infrastructure (production facilities, pipelines, and refineries) that are needed to accommodate the growth in oil sands production.

Earlier, they succeeded in getting Congress to include a provision in 2005 energy legislation that prohibits U.S. government agencies from using petroleum products made from oil sands, shale oil and liquefied coal. The Air Force has objected strongly to this ban, pointing out that it prevents military aircraft from using jet fuel made from oil sands.

California and Oregon have banned use of oil sands, oil shale and liquefied coal, and several northeastern states reportedly plan to follow suit. At the same time, the U.S. House of Representatives is considering legislation that would impose a national ban in the guise of a low-carbon fuel standard. House members who are pushing for its passage seem heedless of economic consequences.

Quite simply, lawmakers should steer clear of regulations that discriminate between conventional and unconventional fuel sources, as they would exacerbate energy security problems without delivering compensating climate benefits. Imposing greater costs on oil sands producers and the liquefied coal sector will only benefit OPEC and would have little impact on reducing greenhouse-gas emissions. Given this country’s increasing rate of unemployment, we can ill-afford to turn our back on unconventional fuels.

Take liquefied coal. Helped by rising energy prices and new research, coal is moving to the forefront as a cleaner-burning fuel and a source for liquid fuel. The technology for converting coal into diesel and jet fuel is well established, having been used for nearly 100 years in Germany and for several decades in South Africa.

Plans for two-dozen major coal-to-liquid projects in the United States are under way. Some of the projects are awaiting federal loan guarantees so that construction can begin. Importantly, research has shown how to capture carbon dioxide at coal facilities and store the gas in the earth's subsurface.

As for Western oil shale, the technology for tapping it is still being developed. But policymakers are counting on oil shale to help meet the nation’s energy needs in future years. In fact, Western shale is far and away Americas most abundant source of oil. Shale in Colorado, Utah and Wyoming holds an estimated 800 billion barrels of recoverable oil. And there is no doubt its development could obviate the need for imported oil.

As the administration works with Congress to develop energy policies, those who shape legislation need to wake up and realize that our country cannot afford to forego the use of unconventional oil. A misguided push to prevent its use can only succeed in undermining our economy.

C. John Mann is a professor emeritus of geology at the University of Illinois at Urbana-Champaign.

----------------

We all "need to wake up and realize that our country cannot afford to forego the use of unconventional oil".

And, it's way past time Coal Country journalists started pouring the coffee.

New York City (!!!) Improves Coal Liquefaction

 
Without preamble, the excerpt: 

"Improvement of coal direct liquefaction by steam pretreatment

Authors

IVANENKO O. ; GRAFF R. A. ; BALOGH-NAIR V. ; BRATHWAITE C. ;

Authors Affiliations

Departments of Chemical Engineering and Chemistry, The City College of New York, New York, New York 10031, ETATS-UNIS

Abstract

Pretreatment of coal by reaction with subcritical steam enhances its performance in direct liquefaction. Illinois No. 6 coal, first reacted with 51 atm of steam for 15 min at 340 °C, was liquefied in a coal injection autoclave to provide rapid heating. Liquefactions were carried out with raw and pretreated coal at high-severity (400 °C, 30 min) and low-severity (385 °C, 15 min) conditions under 1500 psia of hydrogen with tetralin as the donor solvent. Substantial improvement in product liquid quality is realized provided the pretreated coal is protected from oxygen and heated rapidly to liquefaction temperature. Under low-severity conditions, the oil yield is more than doubled, going from 12.5 to 29 wt %. Since previous work pointed to the destruction of ether cross-links by water as the dominant depolymerization mechanism during pretreatment, tests were conducted with several aromatic ethers as model compounds. These were exposed to steam and inert gas at pretreatment conditions and in some cases to liquid water at 315 °C. α-Benzylnaphthyl ether and α-naphthylmethyl phenyl ether show little difference in conversion and product distribution when the thermolysis atmosphere is changed from inert gas to steam. Hence, these compounds are poor models for coal in steam pretreatment. The otherwise thermally stable 9-phenoxyphenanthrene, on the other hand, is completely converted in 1 h by liquid water at 315 °C. At pretreatment conditions, however, mostly rearranged starting material is obtained. Therefore, 9-phenoxyphenanthrene, though less reactive, is a model for ether linkages in coal. 

Journal

Energy & Fuels; 1997, vol. 11, pp. 206-212

Publisher

American Chemical Society, Washington, DC, ETATS-UNIS  (1987) (Revue)"
 
So, a college, in New York City, is improving a process for the direct liquefaction of coal into liquid fuels. We're glad that it's a United States institution, at least. But, what about the institutions of higher learning in Coal Country? Well, you do recall our dispatch of yesterday regarding the conversion of BS and dead horses' patoots, don't you?

CO2 Recycling: Trees to Plastics

 
We've documented, in our posts to the WV Coal Association R&D Blog, that, not only can coal be converted in economical and responsible ways into the variety of liquid fuels and plastics manufacturing raw materials that we, as a modern industrial nation, need, the primary by-product of coal use, Carbon Dioxide, can itself be directly captured and recycled into those same fuels and plastics.
 
We've also documented that botanical materials, such as cellulose, can also be converted into liquid fuels using the same technologies as are used for coal liquefaction, and even as a co-feed raw material with coal in the same, appropriately-specified, process stream.
 
Such botanically-derived cellulose-to-fuel technology represents an inherent route of Carbon Dioxide recycling, and it avoids capital expense that might be required for direct CO2 capture and processing.
 
We have, as noted, shown that coal can be converted into plastics manufacturing raw materials, as is being done by Eastman Chemical in Kingsport, Tennessee.
 
Cellulose has the same potential, as well. And, as with direct Carbon Dioxide recycling, into methanol that would be used for the manufacture of plastics as opposed to liquid fuel, such practice of converting cellulose into plastic would represent an essentially permanent, and profitably productive, route of "sequestration" for atmospheric Carbon Dioxide.
 
Eastman Chemical, as per the article linked above, has developed such technology. An extended excerpt from their site follows. Keep in mind, as you read it, that the cellulose they use to make these valuable, lasting products, is a material that recycles, in a very "Green", ecologically-responsible fashion, the primary by-product of our coal use industries, and "sequesters" it in a way that should be more than satisfactory to all but the Big Oil lackeys, who hope to coerce our coal industries into pumping, at all our expense, CO2 deep into the earth - to force out more petroleum they can further extort us, and enrich themselves, with.
 
The excerpt has been edited somewhat to improve length and clarity. As always, we urge our readers to access the site through the link for more information.
 

The Process of Making Trees into Plastic

Eastman Chemical Company 

From Trees to Plastic
Trees to Cellulose 4.78 lb of wood chips = 1 lb of cellulose
Cellulose to Ester 0.59 lb of cellulose = 1 lb of ester
Ester to Plastic 0.92 lb of ester = 1 lb of plastic
Trees to Plastic2.60 lb of wood chips = 1 lb of plastic

From Trees to Cellulose

In the process of converting trees to cellulose, little is wasted. The bark is removed before pulping and is used as fuel for the conversion process itself. The tree is chipped and then cooked in a digester to separate cellulose fibers. Lignins and resins produced at this stage can also be used for other chemical products or as fuel.

The resulting pulp of alpha cellulose and hemicellulose is treated with various bleaching chemicals to reduce the hemicellulose content and remove the last traces of lignins and resins. At this stage, the pulp is clean and white. It is pressed to remove water, then dried and wound onto rolls. This is the high-quality, high-alpha cellulose used to manufacture cellulose esters for plastics. Only the highest-quality pulps are used for Tenite cellulosics

From Cellulose to Ester

Cellulose esters are made by reacting high-purity cellulose with selected acids and anhydrides in a multistage process. The choice of acids and anhydrides determines the chemical composition and properties of the final Tenite cellulosic plastic; the cellulosic plastics—acetate, butyrate, and propionate—are chemically different.

In esterification and hydrolysis, the cellulose, acids, and anhydrides are reacted under controlled catalyst concentrations and temperatures to determine the chemical make-up and viscosity of the cellulose ester. A viscous solution—the cellulose ester dissolved in acid—is formed at this stage. The solution then undergoes ultrafine filtration to remove traces of unreacted cellulose fibers and by-products. This ultrafine filtration is critical in making high-quality material required for injection molding and extrusion applications. Then, in a process known as precipitation, the cellulose esters are separated from the viscous solution of water and acids as a solid powder. Following precipitation, the cellulose esters are washed to remove residual acids, then dried.

From Ester to Plastic

Cellulose ester, plasticizer, and additives are compounded in the final manufacturing step to produce the finished cellulosic plastic.

A custom compounder of cellulosics since 1932, Eastman produces Tenite acetate, butyrate, and propionate in a variety of formulations and plasticizer content ranging from 3% to 35% in 3.2-mm (1/8-in.) pellets for molding and extrusion. 

Tenite cellulosic plastics, the first of the modern thermoplastics, have been used for more than 60 years because they:

  • Have an excellent balance of properties, including toughness, hardness, strength, surface gloss, clarity, chemical resistance, and a warm feel.
  • Are available in a variety of formulas, plasticizer levels, and additives.
  • Are easily molded, extruded, and fabricated.
  • Are resistant to attack or change by a wide variety of common household, industrial, and medical chemicals.
Properties

Tenite cellulosic plastics, noted for their excellent balance of properties, are available in a variety of formulas and plasticizer levels and can be tailored to the requirements of the user.

Mechanical
Tenite acetate, butyrate, and propionate are specified by the percentage of plasticizer.

The mechanical properties of Tenite cellulosic plastics differ with plasticizer level. The type and amount of plasticizer affects the mechanical properties of the plastic. Lower plasticizer content yields a harder surface, higher heat resistance, greater rigidity, higher tensile strength, and better dimensional stability; higher plasticizer content increases impact strength.

Electrical

Electrical properties of Tenite acetate, butyrate, and propionate are similar. All have a high dielectric constant, good dielectric strength and volume resistivity, and a high dissipation factor.

Chemical Resistance

Tenite cellulosic plastics are characterized by exceptional resistance to chemically induced stress cracking. Tenite cellulosics are resistant to attack or change by a wide variety of common household, industrial, and medical chemicals such as toothpaste, aliphatic hydrocarbons, bleach, detergents/soaps, ethylene glycol, salt solutions, vegetable and mineral oils, alcohols, and lipids.

Cellulosics are frequently chosen not only for their good balance of properties and ease of processing but also for their extraordinary appearance characteristics.

Special formulations of Tenite butyrate and propionate for outdoor applications or formulations that meet FDA regulations are available.